Some programs are intellegent in the way that they mix like IRL paints do. http://www.artrage.com/ Artrage is a program that is written to SPECIFICALLY replicate traditional media, and apparently it's really close. I don't know cause tablets aren't enjoyable for me to use so I don't do digital art often, but my friend Hannah swears by it. It's cheep to buy the full version of it too in comparison to Photoshop too.
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